Hi,
In 1940 two chemists named Sidgwick and Powell came up with a theory on the structures of molecules and were the first to introduce the linear, trigonal planar, tetrahedral, trigonal bypyramid, and octahedral geometries. Although they developed the key molecular geometries, their theory was incorrectly stated: "Bonding pairs and lone pairs are of equal importance and distribute themselves to minimize interelectron repulsion." What fundamental modification did Gillespie and Nyholm add to Sidgwick and Powell's theory to develop the VSEPR theory that we use today? Give an example of two different molecules that violate the incorrect statement in the Sidgwic/Powell theory and give evidence as to why they violate the old theory?
Are bonding pairs more important and they try to get as far from one another as possible? It does seem like the bonding pairs and the lone pairs are of equal importance so I don't know what's wrong.
Thanks!
2007-11-19
09:14:21
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3 answers
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asked by
Anonymous