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Hard water contains limestone particles that corrode soap

2007-11-29 13:37:43 · answer #1 · answered by Aris Molokai 2 · 0 0

Because soap is (mostly) the sodium salt of a long-chain fatty acid like stearic: CH3(CH2)16COO-Na+. The long CH2 chain solubilizes grease and oil. The -COO-Na+ head solubilizes the whole thing in water. But hard water has Ca++ and Mg++ ions in it, whose stearates are water insoluble. These are responsible for soap scum and "ring-around-the-bathtub. So first you have to precipitate those ions, then the rest of the soap is available for washing your hands. Detergents with -SO3-Na+ heads do not have insoluble Mg++ or Ca++ salts, and so you can use them for washing in hard water.

2007-11-29 13:36:24 · answer #2 · answered by steve_geo1 7 · 1 0

You get more lather with soft water (because you have less minerals or something like that), so it feels like you need more soap with hard water.

2007-11-29 13:32:23 · answer #3 · answered by Anonymous · 0 1

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