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Suppose you do a GC analysis on a sample consisting of 15% A, 60% B, and 25% C by weight. A and B are volatile and have different retention times but C is nonvolatile under the conditions used and therefore does not generate a peak on the chromatogram. Assuming that you do not know that there is nonvolatile material in the sample, what will you conclude from the GC analysis,ie.,what percent of A and B would you calculate?

2007-09-28 08:35:31 · 2 answers · asked by Anonymous in Science & Mathematics Chemistry

2 answers

20% A, 80% B.

2007-09-28 08:38:43 · answer #1 · answered by Steve C 7 · 2 0

The peaks would still come over in the same ratio of 15%/60%

but they would have to be normalized to make the result = to 100%

60 + 15 = 75 to make this go to 100 you'd multiple by approximately 100/75 = 1.333

so the peaks would come out as A = 60 * 1.333 ≈ 80 %

and

B = 15 * 1.333 ≈ 20 %

2007-09-28 08:45:23 · answer #2 · answered by Dr Dave P 7 · 1 0

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