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Just to make sure I have the right answer. When doing a simple distillation, the reason why the liquid in the distillation flask doesn't evaporate all at once once the boiling point is reached is: the liquid distillated is separated from the volatile liquid still in the conical vile. You are purifying the liquid so not all the substance can be vaporized all at once.

2007-09-25 18:34:29 · 3 answers · asked by iheartdr.sambeckett 4 in Science & Mathematics Chemistry

3 answers

A simple distillation is anything but "simple" in terms of what you get from it. For one thing, you do NOT get the pure lowest-boiling compound first, unless the rest of the liquids are so high-boiling that they have virtually no vapor pressure at the boiling point of the most volatile liquid. Only fractional distillation can separate them reasonably well, and then only if they don't form constant-boiling mixtures or azeotropes.

What happens when the contents of the flask start to boil is that the vapor pressure builds to the point where it is finally greater than the atmospheric pressure. Some of the vapor reaches the condenser and is liquefied there to flow into the collection flask. Some of it condenses before it reaches the condenser and falls back into the distillation flask. There is always an equilibrium between evaporation and condensation, because once the vapors reach the area above the flask, they are cooled by the lack of external heating there. That part does gradually warm up from the heat of the vapors as they condense, but it can never get as hot as the liquid in the flask. The only thing that drives the distillation away from equilibrium and toward emptying of the distillation flask is the removal of the condensate as it reaches the condenser and exits the system.

2007-09-25 19:08:26 · answer #1 · answered by Anonymous · 0 0

you will desire to be far extra particular whilst relating 'compounds'. Are we conversing approximately proteins, different polymers, small molecules, hydrocarbons and so forth.? As for distillation, that's the technique of heating a combination such that a number of of of the aspects evaporates, travels via a condenser and condenses in yet another vessel. Fractional distillation is a sort of distillation the place the vapor is a combination itself. In a extreme temperature surroundings the smallest molecules will upward thrust to the suitable and the heavier stay close to the backside. The vapor is extracted at various heights interior the fractionating column. The ensuing distillates would be extra organic than in case you had only used established distillation yet via no ability definitely organic. this is between the procedures wherein petrol is acquired. i do now not comprehend what you're asking interior the final 2 questions. attempt including some verbs in there.

2017-01-02 16:59:29 · answer #2 · answered by bedward 4 · 0 0

First the component with the lowest boiling point evaporates completely. after further heating the second component evaporates completely and so on

2007-09-25 18:43:08 · answer #3 · answered by maussy 7 · 0 1

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