2007-09-22 21:52:36 · 3 answers · asked by Anonymous in Science & Mathematics ➔ Chemistry
Aldehydes from Grignard reagents with formic acid.
www.erowid.org/archive/rhodium/chemistry/grignard.formic.html
The Reaction between Potassium Permanganate and Formic Acid
journals.iucr.org/b/issues/1977/07/00/a14817/a14817.pdf
The free acid, when heated with concentrated sulphuric acid, is decomposed into water and pure carbon monoxide; when heated with nitric acid, it is oxidized first to oxalic acid and finally to carbon dioxide. The salts of the acid are known as formates,
http://www.1911encyclopedia.org/Formic_acid
ACETIC FORMIC ANHYDRIDE:[Acetic acid, anhydride with formic acid]
http://www.orgsyn.org/orgsyn/orgsyn/prepContent.asp?prep=cv6p0008
Use of formic acid in controlling the rate of the Michael Addition
findarticles.com/p/articles/mi_hb3503/is_199306/ai_n8302572 - 24k
In the reduction part of the reaction, formylimine reacts with formic acid to produce formylamine.
acs.confex.com/acs/green07/techprogram/P41642.HTM
2007-09-23 00:47:34 · answer #1 · answered by Anonymous · 0⤊ 0⤋
Yes -
1. reaction with sodium hydrogencarbonate
2. reaction with ethanol in the presence of conc. H2SO4 to make an ester
3. dehydration reaction with conc. H2SO4 to make carbon monoxide
2007-09-22 22:11:01 · answer #2 · answered by Gervald F 7 · 1⤊ 0⤋
lot of answers you got and i want to give one named reaction for you that is clark reaction for using N-methylation along with formaldehyde+primary amine.
mail me to pgr_43@yahoo.co.in
2007-09-23 02:22:26 · answer #3 · answered by ganga 1 · 0⤊ 0⤋