The first "friction match" was invented by English chemist John Walker in 1827. Early work had been done by Robert Boyle in the 1680s with phosphorus and sulfur, but his efforts had not produced useful results. Walker discovered a mixture of antimony(III) sulfide, potassium chlorate, gum, and starch could be ignited by striking against any rough surface. Walker called the matches congreves, but the process was patented by Samuel Jones and the matches were sold as lucifers. The early matches had a number of problems - the flame was unsteady and the initial reaction was disconcertingly violent; additionally, the odour produced by the burning match was unpleasant. It is described as a firework odor. Despite these problems, the new matches were responsible for a marked increase in the number of smokers. Lucifers reportedly could ignite explosively, sometimes throwing sparks at a considerable distance.
In 1831, Frenchman Charles Sauria added white phosphorus to remove the odor. These new matches had to be kept in an airtight box but were popular. Unfortunately, those involved in the manufacture of the new matches were afflicted with phossy-jaw and other bone disorders, and there was enough white phosphorus in one pack to kill a person. There was a vociferous campaign to ban these matches once the dangers became known.
source:wikipedia
2007-03-19 03:16:43
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answer #1
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answered by purimani2005 4
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