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Why do we need ether to form a grinard reagent? More specifically, why does it need to be anhydrous ether?

Reaction Example:

Ar-Br + Mg, ether = Ar-MgBr
(Ar is an aromatic ring)

2007-11-07 12:10:35 · 2 answers · asked by Chemnerd 1 in Science & Mathematics Chemistry

2 answers

We need ether, because nothing else seems to work. It must be anhydrous because:

Ar-MgBr + H2O ===> ArH + Mg++ + Br- + OH-

2007-11-07 12:16:01 · answer #1 · answered by steve_geo1 7 · 0 0

Aluminum will engage in unwanted side reactions if there is water present. A Grignard reagent can be used with alkanes as well as aromatics.

2007-11-07 20:14:28 · answer #2 · answered by Anonymous · 0 0

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