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At equilibrium, the value of the reaction quotient, Qp, is 0.636. What will be the value of Qp if the total pressure of the reaction shown below is doubled?

A (g) ↔ 4 B (g)

the answer is 5.09 but why?

2007-10-29 10:38:57 · 1 answers · asked by Anonymous in Science & Mathematics Chemistry

1 answers

5.09 = 0.636*8, so doubling the pressure increases Qp by a factor of 8. Qp normally depends on concentration. Doubling the pressure reduces volume to 0.5 times its original value, doubling the concentration. Reaction rate in a reversible reaction A <--> B is governed by Qp = [B]^x / [A]^y. Since [A] / [B] remains unchanged, it must be the case that x - y = 3 so that Qp depends on the cube of the concentration of B. If the concentration doubles, Qp increases by a factor of 8.

2007-11-01 03:29:39 · answer #1 · answered by DavidK93 7 · 0 0

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