What are the major organic product(s) from the following reactions? (Where?

Question

A. Ph-CH2CH2CH3 -----Br2/ hv--------->

B. Ph-CH2CH2CH3 --------Br2/FeBr3----->

C. Ph-CH2CH2CH3 -------SO3----->

D. Ph-NO2 -------CH3Cl/ AlCl3------->

E. HO3-Ph-CH3 ------CH3Cl/AlCl3----->

Answer 1

A. Ph-CHBr-CH2-CH3 + Ph-CH2-CHBr-CH3 + Ph-CH2CH2CH2Br

B. 4-Br-C6H4-CH2CH2CH3 ( plus a little bit of 2-Br-C6H4-CH2CH2CH3

C. 4-HO3S-C6H4-CH2CH2CH3

D. No reaction, because nitrobenzene is too deactivated by the nitro group to undergo the Freidel-Crafts reaction.

E. 2,6-Dimethyl-1,3,5-benzenetriol