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What is the molality of the resulting solution?

2007-07-06 06:06:06 · 4 answers · asked by Anonymous in Science & Mathematics Chemistry

4 answers

Atomic weights: C=12 H=1 O=16 C2H6O2=62 H2O=18

Let ethylene glycol be called EG

If the mole fraction of EG is 0.111, then that of water is 1.000 -0.111 = 0.889.

0.889molH2O x 18gH2O/1molH2O = 16gH2O

0.111molEG/16gH2O x 1000gH2O/1kgH2O = 6.93 mol EG/1kgH2O

This is the molality, because molality is number of moles solute (EG) in 1 kg solvent (H2O).

2007-07-06 06:14:50 · answer #1 · answered by steve_geo1 7 · 1 1

Let m be molality.

m = (weight of solute x 1000) / ( molar mass of solute x weight of solvent)

All weights are in g and molar mass is in g/mol.

Let X be the mole-fraction of ethylene glycol.
a is solvent and b is solute (ethylene glycol).
X = 0.111 = Nb/ Na + Nb
=> 111/1000 = Nb/Na +Nb
=> 111Na + 111Nb = 1000Nb
=> 111Na = 889Nb
=> Nb/Na = 111/889
=> (wt. of b/ molar mass of b) / ( wt. of a / molar mass of a) =111/889

Now, molar mass of a, H2O is 18g/mol
molar mass of b, HOCH2CH2OH is 62 g/mol
=> (wt. of b/62) / (wt.of a / 18) =111/889
=> wt. of b/ wt.of a = 0.43007

Using the above ratio in the general eqn of molality;

m = ( wt. of b) x 1000 / (wt.of a ) x molar mass of b
m = (0.43007 x1000)/ 62
=430.07/62
= 6.936 mol (Ans.)

2007-07-06 06:29:15 · answer #2 · answered by Shobiz 3 · 0 0

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2016-05-17 00:09:35 · answer #3 · answered by Anonymous · 0 0

Find out the moles.

2007-07-06 06:34:51 · answer #4 · answered by ag_iitkgp 7 · 0 2

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