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why does the linear spectrum emitted ONLY in seprate atoms or gaseous state under low pressure?

2007-04-27 03:54:01 · 1 answers · asked by Anonymous in Science & Mathematics Physics

1 answers

I think by linear you mean containing discrete emission lines. These lines are produced by orbital electrons changing orbit in a given atom, and the energy change is quantized, resulting in emission of photons with a specific energies and therefore light of a specific color. This is called an emission spectrum.
When the atoms/molecules are close together, collisions due to thermal motion occur, and the energy of the collisions is variable and has a wide distribution, resulting in a continuous spectrum.
With low molecular density such as in a low-pressure gas, the emission spectrum predominates. As molecular density increases (as in a solid or high-pressure gas), the continuous spectrum becomes more and more dominant. See the references.

2007-04-27 13:44:40 · answer #1 · answered by kirchwey 7 · 0 0

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