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The standard enthalpy of combustion for xylene, C8H10(l), is –3908 kJ mol-1. Using this data and the standard enthalpies of formation, : H2O(l) = –285.9 kJ mol-1; CO2(g) = –393.5 kJ mol-1, calculate the standard enthalpy of formation of C8H10(l), in kJ mol-1.

2007-04-17 20:33:13 · 2 answers · asked by stringbeans 2 in Science & Mathematics Chemistry

2 answers

We first write the combustion equation
Enthalpy of Combustion is –3908 kJ mol-1
Enthalpy of Formation of H20 is –285.9 kJ mol-1
Enthalpy of Formation of CO2 is –393.5 kJ mol-1

Let get Start

C8 + 5H2 -> C8H10 Hc = -3908
Enthalpy of Formation of C8H10 = - (Enthalpy of Combustion ) + Enthalpy of Formation of H20 + Enthalpy of Formation of CO2

:. Enthalpy of Formation of C8H10 = -(-3908) + 8(–393.5 ) + 5(–285.9)
:. Enthalpy of Formation of C8H10 = 3908 -3148 -1429.5
= -669.5 kJ mol-1.

2007-04-17 22:14:59 · answer #1 · answered by Tubby 5 · 2 0

C8H10 + 21/2 O2 -> 8CO2 + 5H2O

Heat of formation of C8H10 = -(-3908 + 8*393.5 + 5* 285.9)

= -669.5 kJ/mol

2007-04-18 04:56:10 · answer #2 · answered by ag_iitkgp 7 · 1 1

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