polydentate ligands result in more stable complex ions
then do monodentate ligands
An example of formation equilibrium for a complex ion in solution is:
Al3+ + 6F− ↔ [AlF6]3− Kf = 5.0 × 10−3
ΔG = −RT ln( Kf )
remember, the more negative the value the of ΔG the more stable
are the products of reaction that are formed
Which of the following are true statements ?
a) en stands for ethylenediamine, a bidentate ligand
b) The subscript f in Kf stands for 'free energy'
c) A very small value of Kf for a chemical reaction in which a coordination complex
is a product would indicate that the complex formed is a relatively stable one
d) A very large value of Kf for a chemical reaction in which a coordination complex
is a product would indicate a relatively small decrease in Gibbs free energy
2007-04-13
09:06:12
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2 answers
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asked by
Anonymous
in
Science & Mathematics
➔ Chemistry