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I am having some trouble with triprotric acids, so I was hoping someone could help me. My teacher gave the following example, and I am quite stumped, any help would be appreciated.
The question is: Citric acid (C6H5O7H3) is a troprotic acid because it has three acidic hydrogen ions to donate. Write the 3 equations that would describe how citric acid would react with water and donate its hydrogen ions.

Any help you can give would be appreciated. Thanks

2007-04-11 14:37:41 · 3 answers · asked by Bryton 1 in Science & Mathematics Chemistry

3 answers

Formula of citric acid is C6H8O7 our top contributor lost it on this one ...

Anyway
H3C6H5O7 + H2O = H2C6H5O7^(-) + H3O^(+)
H2C6H5O7H2- + H2O = HC6H5O7^(2-) + H3O^(+)
HC6H5O7H^(2-) + H20 = C6H5O7^(3-) + H3O^(+)

2007-04-11 15:04:58 · answer #1 · answered by Sarkasme 2 · 0 0

In general, acid + water <---> H3O+ + conjugate base

C6H5O7H3 + H2O <---> H3O(1+) + C6H5O7H2(1-)
This is a weak acid equilibrium, with its own constant K1

C6H5O7H2(1-) + H2O <---> H3O(1+) + C6H5O7H1(2-)
Equilbrium constant K2

C6H5O7H1(2-) + H2O <---> H3O(1+) + C6H5O7(3-)
Equilibrium constant K3

For triprotic acids, K1 > K2 > K3

2007-04-11 14:45:46 · answer #2 · answered by pandNH4 2 · 0 0

Citric acid is actually H3C6H6O7 (your teacher forgot the H on the -OH group).

H3C6H6O7 + H2O ===> H3O+ + H2C6H6O7-

H2C6H6O7- + H2O ===> H3O+ + HC6H6O7=

HC6H6O7= + H2O ===> H3O+ + C6H6O7^3-

2007-04-11 14:48:15 · answer #3 · answered by steve_geo1 7 · 0 0

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