state of iodine. what is the oxidation state of iodine in the product?
Reaction under Andrews’ conditions
In the next titration you will see that the same oxidant, IO3-, and reductant, I-, can undergo a different reaction by altering the conditions. The reaction will again be done in acidic solution, but this time will contain a large concentration of Cl- (obtained by adding concentrated hydrochloric acid to the reaction vessel). This titration will also illustrate yet another visual means of detecting the end-point.
Weigh accurately about 2.0 g of potassium iodide and make it up to 250 ml of aqueous solution in a volumetric flask. Transfer 25 ml of this solution by pipette to a 250 ml stoppered bottle, then add 25 ml of water, 60 ml concentrated hydrochloric acid (CARE – CORROSIVE - do this procedure at the sink), and about 5 ml of CH2Cl2 (TAKE CARE - do this procedure in the fume hood). Cool the bottle to room temperature, then add, from a burette, a standard 0.
2007-03-24
06:01:40
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Science & Mathematics
➔ Chemistry