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CH3CH2CH2COHCH2CH3 +CH3CH2CH2CH2C=O H

the last reactant ends with a aldehyde, i was just not sure how to type it out. did my best.

i think the end product would be an hemiacetal because i'm adding an alchol to a aldehyde. it would be an acetal if i added an alchol to an acetal, right?

2007-02-14 01:30:34 · 2 answers · asked by Anonymous in Science & Mathematics Chemistry

i meant to say it would be an acetal if i added an alcohol to a hemiacetal

2007-02-14 01:36:46 · update #1

2 answers

Dr. David P. is indeed correct. If you just put the alcohol and aldehyde together, you would get a hemiacetal. That reaction is a simpkle addition and occurs spontaneously.You are also correct to say that reaction of a hemiacetal with alcohol would yield an acetal. However, that is a condensation, splitting out a molecule of water. You would have to add an acid such as H2SO4 or p-H3C-C6H4-SO3H and distil to drive out the water and shift the equilibrium. Sometimes people add a little benzene to distil out an azeotrope of benzene, alcohol, and water.

2007-02-14 02:24:49 · answer #1 · answered by steve_geo1 7 · 0 0

Hemiacetal.

PrCH(OH)-Et + Pr-CHO --> Pr-CH(OH)-O-CH(Pr)-Et

reaction with a ketone and an alcohol gives an acetal.

reaction of a aldehyde and an alcohol gives an hemiacetal

2007-02-14 09:34:18 · answer #2 · answered by Dr Dave P 7 · 0 0

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