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In the presence of melted NaOH and NaNo3, Mn (IV) can be oxidized to Mn (VII), with formation of NO2 negative. Can anyone help with the equation for this reaction

2007-02-07 02:44:59 · 1 answers · asked by Lost...i think 1 in Science & Mathematics Chemistry

1 answers

2NaOH + 2MnO2 + 3NaNO3 ===> 2NaMnO4 + 3NaNO2 + H2O

I solved it by half-reactions. First I wrote and balanced,

H2O + NaNO3 + 2e- ===> NaNO2 + NaOH

Next,

NaOH + MnO2 ===> NaMnO4 + 3e- + H2O

After balancing the half reactions, I multiplied one by 2 and the other by 3 to get 6 electrons lost and gained in each. Then I added them together. The electrons cancelled.

2007-02-07 03:13:51 · answer #1 · answered by steve_geo1 7 · 1 0

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