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At a certain temperature the reaction

SO2Cl2 → SO2 + Cl2

is a first order reaction with t1/2 = 153.0 x 102 sec

What is the rate constant for this reaction (1/sec) ?


Enter a numeric answer only, do not include units in your answer

2007-02-05 05:51:02 · 2 answers · asked by geebgeebgeeb 1 in Science & Mathematics Chemistry

2 answers

t1/2 = Ln2/k = 0.69315/k

k = 0.69315/(1.53x10^2) = 4.62 x 10^-5

Three significant figures.

2007-02-05 06:04:12 · answer #1 · answered by steve_geo1 7 · 0 0

rate constant(k) for a first order reaction in terms of t1/2 is given by:

k=0.693/t1/2 or log2/t1/2

and therefore ur answer will be:

k=0.693/153 x 102= 4.53 x 10 ^ -5

2007-02-05 06:06:03 · answer #2 · answered by Anonymous · 0 0

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