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this is exception;but reason what i think that in -i containing group there is partial shifting of electron cloud which create partial +ive on c but this cannot be happen in formic acid.

2007-01-29 23:47:21 · 2 answers · asked by dr.amit 1 in Science & Mathematics Chemistry

2 answers

u know when O will loose H -ve charge will come on it and in formic acid this -ve charge will get stablised by resonance

whereas in other one as cl is -i grp the effective resonance will not be effective as in formic due to delta +ve charge on carbon to which CL is attached

that is why more the resonance more stablise dwill b the structure hence more acidic will b formic acid

2007-01-30 20:11:09 · answer #1 · answered by n nitant 3 · 0 0

the reason might be the absence of methyl or i.e. alpha carbon in formic acid. as in ethanoic acid, the methyl group (due to +I effect) shifts electrons towards the carbonyl carbon ,, thus stabilizing the positive charge on the carbonyl carbon
in 2-chloro ethanoic acid, even though an electron withdrawing group (-Cl) is present , i think the electron releasing effect of the methyl group is more.
and as formic acid does not have an electron releasing group, it is more acidic than 2chloro ethanoic acid

2007-01-30 08:09:02 · answer #2 · answered by confused seeker... 2 · 0 1

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