Phenolphthalein or methyl orange. Because the acid and base to be used are strong ones, it doesn't matter that the endpoint is a pH slightly off 7. Phenolphthalein is pH=8 and methyl orange is on the acid side, maybe 6.
2007-01-18 03:22:18
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answer #1
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answered by steve_geo1 7
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Think about what you're adding together. For the sake of simplicity, let's define an acid as anything that gives a proton to a solution, and a base as anything that gives an OH to a solution. Acids and bases are termed "strong" or "weak" based on their ability to give away their H+ or OH- groups. A strong acid gives away its H+ as soon as it comes into contact with water, and cannot take it back. A strong base steals and H+ from the water, and makes an OH- in solution, but is really bad about returning the OH-. A weak acid gives H+, but it can also take it back in a reversible reaction. A weak base takes an H+ to make OH-, but can also give backs its H+ in a reversible reaction. Every weak acid has a twin that is a weak base, just missing its proton. So, if you put strong and strong, they react violently. If you put in an equal number of moles of each, the moles of H+ and the moles of OH- will get together and make a mole of water. So, every acid molecule and every base molecule have a partner, the pH will be neutral (7) 'cause they've cancled everything else out. With a strong/weak titration, things go a little bit differently. The two are essentially the same, though, in principle, and work by the same mechanism. Let's look at an strong base/weak acid titration, 'cause they're really common. As you add the strong base to the mixture, it pulls H+ away from the acid, and makes the conjugate base. But, that weak base pulls H+ from water, and makes OH-! So, when you have neutralized all the acid in the mixture, your final pH will actually be a little bit higher than 7 because of the equilibrium. When you have a weak acid and a strong base, the final pH is lower than 7. When you do a weak/strong titration, you can find the pKA, or the pH at which the concentration of acid/base conjugate pair twins are equal. This happens at the pH which corresponds to exactly half the volume of acid added. If you're in a lab working with a burette and color indicator, the point can sometimes be hard to find. Colorimetric titration is an art-form. If you have a pH meter, make a plot of pH vs. volume added. Then, take the second derivative of the line. The second derivative of this plot is 0 at the equilivance point.
2016-03-29 03:08:33
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answer #2
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answered by Anonymous
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Many methods can be used to indicate the endpoint of a reaction; titrations often use visual indicators (the reactant mixture changes colour). In simple acid-base titrations a pH indicator may be used, such as phenolphthalein, which turns (and stays) pink when a certain pH is reached or exceeded. Methyl orange can also be used, which is red in acids and yellow in alkalis.
The excerpt above is from the source below:
2007-01-18 03:24:58
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answer #3
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answered by Anonymous
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depends on which acid and base you're talking about. I'd start with phenolphthalein
2007-01-18 04:57:24
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answer #4
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answered by shiara_blade 6
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tak an indicator where the indicator has a noticeable change in colour..avoid bromothymol blue..as the colour change is slitely noticeable..use methyl orange..or phenolphtalene...gud luck..
2007-01-18 03:30:44
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answer #5
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answered by lUnJ@ 3
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