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Which member of the following pairs has the stronger intermolecular dispersion forces:

Br2 or O2

CH3CH2SH or CH3CH2CH2SH

CH3CH2CH2Cl or (CH3)2CHCl

and if possible could you explain how you found it.

2006-12-18 07:07:44 · 2 answers · asked by bosox1989 1 in Science & Mathematics Chemistry

2 answers

compounds with more H-bonds (can only be Hydrogen bonded with either Flourine, Oxygen, and Nitrogen) Those have stronger intermolecular forces. Anything with higher electronegativity has stronger forces. Also Dipole-Dipole must occur (polar).

O2 is stronger more electronegativity (shorter bond=stronger Lattice energy)
CH3CH2CH2SH stronger contains more electrons
CH3CH2CH2Cl stonger

2006-12-18 07:23:47 · answer #1 · answered by xashleyleyx 4 · 0 1

Br2

CH3CH2CH2SH

These two above have more electrons than their counterparts and can make better dispersion forces

CH3CH2CH2Cl

This one is a more 'linear' molecule than its nearly spherical couterpart and it can have more points of contact with other moluecules so that it has better bonds

2006-12-18 15:16:31 · answer #2 · answered by Anonymous · 1 0

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