What are the causes of ozone in the Stratosphere?

Answer 1

The photochemical mechanisms that give rise to the ozone layer were worked out by the British physicist Sidney Chapman in 1930. Ozone in the earth's stratosphere is created by ultraviolet light striking oxygen molecules containing two oxygen atoms (O2), splitting them into individual oxygen atoms (atomic oxygen); the atomic oxygen then combines with unbroken O2 to create ozone, O3. The ozone molecule is also unstable (although, in the stratosphere, long-lived) and when ultraviolet light hits ozone it splits into a molecule of O2 and an atom of atomic oxygen, a continuing process called the ozone-oxygen cycle, thus creating an ozone layer in the stratosphere ,the region from about 10 to 50 km (32,000 to 164,000 feet) above Earth's surface. About 90% of the ozone in our atmosphere is contained in the stratosphere. Ozone concentrations are greatest between about 15 and 40 km, where they range from about 2 to 8 parts per million. If all of the ozone were compressed to the pressure of the air at sea level, it would be only a few millimeters thick.

Ten percent of the ozone in the atmosphere is contained in the troposphere, the lowest part of our atmosphere where all of our weather takes place. Tropospheric ozone has two sources: about 10 % is transported down from the stratosphere while the remainder is created in situ in smaller amounts through different mechanisms.


Ultraviolet light and ozone

Levels of ozone at various altitudes and blocking of ultraviolet radiation.Although the concentration of ozone in the ozone layer is very small, it is vitally important to life because it absorbs biologically harmful ultraviolet (UV) radiation emitted from the Sun. UV radiation is divided into three categories, based on its wavelength; these are referred to as UV-A, UV-B, and UV-C. UV-C, which would be very harmful to humans, is entirely screened out by ozone at around 35 km altitude.

UV-B radiation can be harmful to the skin and is the main cause of sunburn; excessive exposure can also cause genetic damage, resulting in problems such as skin cancer. The ozone layer is very effective at screening out UV-B; for radiation with a wavelength of 290 nm, the intensity at Earth's surface is 350 million times weaker than at the top of the atmosphere. Nevertheless, some UV-B reaches the surface. Most UV-A reaches the surface; this radiation is significantly less harmful, although it can potentially cause genetic damage.

Depletion of the ozone layer allows more of the UV radiation, and particularly the more harmful wavelengths, to reach the surface, causing increased genetic damage to living organisms.


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The highest levels of ozone in the atmosphere are in the stratosphere, in a region also known as the ozone layer between about 10 km and 50 km above the surface. Here it filters out the shorter wavelengths (less than 320 nm) of ultraviolet light (270 to 400 nm) from the Sun that would be harmful to most forms of life in large doses. These same wavelengths are also responsible for the production of vitamin D, which is essential for human health. Ozone in the stratosphere is mostly produced from ultraviolet rays reacting with oxygen:

O2 + (radiation < 240 nm) → 2 O
O + O2 → O3
It is destroyed by the reaction with atomic oxygen:

O3 + O → 2 O2

The latter reaction is catalysed by the presence of certain free radicals, of which the most important are hydroxyl (OH), nitric oxide (NO) and atomic chlorine (Cl) and bromine (Br). In recent decades the amount of ozone in the stratosphere has been declining mostly due to emissions of CFCs and similar chlorinated and brominated organic molecules, which have increased the concentration of ozone-depleting catalysts above the natural background

Answer 2

Lightning generates most of the ozone in the atmosphere. Most lightning strikes occur in the upper part of clouds. When there is a strong electrical spark, the distinctive smell that it leaves afterwards is caused by ozone.

Addendum: I stand corrected. This is the origin of some low level ozone, as per link below. Most is through photochemical production.