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Calculate the pH of the solution resulting from the addition of 25.0 mL of 0.250M ammonia and 55.0 mL of 0.250 M HCl solution.

I got 5.18 for the pH but im not so certain I did it right, can anyone else solve this and tell me what you got.

2006-10-17 00:26:17 · 2 answers · asked by farxfromxlonelyx 1 in Science & Mathematics Chemistry

2 answers

Find the moles n1 of NH3 and the moles n2 of HCl

n1 = C1*V1 = 0.25*0.025 = 6.25*10^(-3) mol NH3
n2 = C2*V2 = 0.25*0.055 = 0.01375 mol HCl

Find the final volume: Vf = V1 + V2 = 0.025 + 0.055 = 0.08 L

Now, HCl is in excess, NH3 reacts fully:

NH3 + HCl --> NH4Cl

So the final solution contains: n = 0.01375 - 6.25*10^(-3) = 7.5*10^(-3) mol HCl

Find the molarity of HCl in the final solution:

C = n/Vf = 7.5*10^(-3)/0.08 = 0.09375 M

HCl is a strong acid, it reacts fully with water:

HCl + H2O --> H3O+ + Cl-

So [H3O+] = 0.09375M and pH = -log[H3O+], pH = -log(0.09375),

pH = 1.03 or pH = 1 approx.

2006-10-17 23:52:23 · answer #1 · answered by Dimos F 4 · 0 0

The 'solid' in 'solid acid' merely skill it as a rule ionizes. Even a susceptible acid, one that as a rule would not ionize, will react with ammonia. you have substantial extra ammonia, so it incredibly is going to likely be alkaline

2016-12-13 09:48:18 · answer #2 · answered by ? 4 · 0 0

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