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Substance W contains 15.2% by mass of sodium and 53% by mass of bromine the rest is O2. When W is thermally decomposed, a white solid, X and oxygen are the only products. An aqueous solution of X gave a cream precipitate, Y, when aqueous silver nitrate and nitric acid are added.
a)Calculate empirical formula of W
b)Name X and Y
c)Work out the balanced equation for the thermal decomposition of W.

2006-10-03 07:12:20 · 2 answers · asked by Anonymous in Science & Mathematics Chemistry

Why do you divide them all by 0.66?

2006-10-03 07:58:48 · update #1

2 answers

First, find the mass of oxygen in 100 g of substance W:

oxygen mass = 100 - 15.2 - 53 = 31.8 g

Divide each element mass by the relative Atomic mass (Ar or atomic weight) of the element:

Na: 15.2/23 = 0.66 mol
Br: 53/80 = 0.66 mol
O: 31.8/16 = 1.98 mol

Now divide each number by 0.66:

Na: 0.66/0.66 = 1, Br: 0.66/0.66 = 1, O: 1.98/0.66 = 3

So the empirical formula of W is NaBrO3

b. 2NaBrO3 -> 2NaBr + 3O2
NaBr + AgNO3 -> NaNO3 + AgBr

So, X is NaBr and Y is AgBr (precipitate)

c. Already answered in (b)

2006-10-03 07:34:11 · answer #1 · answered by Dimos F 4 · 1 0

Oh my goodness!

I'm so glad I am out of school!!!

What are they teaching kids how to make bombs in school these days!?

2006-10-03 07:25:13 · answer #2 · answered by StarrLee 4 · 0 0

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