Crystalline solids are those in which the atoms, ions, or molecules that make up the solid exist in a regular, well-defined arrangement. The smallest repeating pattern of crystalline solids is known as the unit cell, and unit cells are like bricks in a wall—they are all identical and repeating.
There are four types of crystalline solids.
Ionic solids—Made up of positive and negative ions and held together by electrostatic attractions. They’re characterized by very high melting points and brittleness and are poor conductors in the solid state. An example of an ionic solid is table salt, NaCl.
Molecular solids—Made up of atoms or molecules held together by London dispersion forces, dipole-dipole forces, or hydrogen bonds. Characterized by low melting points and flexibility and are poor conductors. An example of a molecular solid is sucrose.
Covalent-network (also called atomic) solids—Made up of atoms connected by covalent bonds; the intermolecular forces are covalent bonds as well. Characterized as being very hard with very high melting points and being poor conductors. Examples of this type of solid are diamond and graphite, and the fullerenes. As you can see below, graphite has only 2-D hexagonal structure and therefore is not hard like diamond. The sheets of graphite are held together by only weak London forces!
Metallic solids—Made up of metal atoms that are held together by metallic bonds. Characterized by high melting points, can range from soft and malleable to very hard, and are good conductors of electricity.
2006-09-06 17:24:16
·
answer #1
·
answered by ted_armentrout 5
·
6⤊
0⤋
The solids in which atoms, ions, or molecules that make up the solid exist in a regular, well-defined arrangement are called crystalline solids. There are four types of crystalline solids.
1. Ionic soilds - made up of positive and negative ions held together by electrostatic forces.
2. Molecular solids - Made up of molecules or atoms held together by London Disperson forces or hydrogen bonds.
3. Atomic solids - Made up of atoms connected by intermolecular forces.
4. Metallic solids - Made up of metal atoms joined together by metallic bonds.
2006-09-06 17:35:17
·
answer #5
·
answered by Rohini karthikeyan 3
·
3⤊
0⤋
In chemistry and mineralogy, a crystal is a solid in which the constituent atoms, molecules, or ions are packed in a regularly ordered, repeating pattern extending in all three spatial dimensions.
Generally, crystals form when they undergo a process of solidification. Under ideal conditions, the result may be a single crystal, where all of the atoms in the solid fit into the same crystal structure. However, generally, many crystals form simultaneously during solidification, leading to a polycrystalline solid. For example, most metals encountered in everyday life are polycrystals. Crystals are often symmetrically intergrown to form crystal twins.
Which crystal structure the fluid will form depends on the chemistry of the fluid, the conditions under which it is being solidified, and also on the ambient pressure. The process of forming a crystalline structure is often referred to as crystallization.
Synthetic bismuth crystalWhile the cooling process usually results in the generation of a crystalline material, under certain conditions, the fluid may be frozen in a noncrystalline state. In most cases, this involves cooling the fluid so rapidly that atoms cannot travel to their lattice sites before they lose mobility. A noncrystalline material, which has no long-range order, is called an amorphous, vitreous, or glassy material. It is also often referred to as an amorphous solid, although there are distinct differences between solids and glasses: most notably, the process of forming a glass does not release the latent heat of fusion. For this reason, many scientists consider glassy materials to be viscous liquids rather than solids, although this is a controversial topic; see the entry on glass for more details.
Insulin crystalsCrystalline structures occur in all classes of materials, with all types of chemical bonds. Almost all metal exists in a polycrystalline state; amorphous or single-crystal metals must be produced synthetically, often with great difficulty. Ionically bonded crystals can form upon solidification of salts, either from a molten fluid or when it condenses from a solution. Covalently bonded crystals are also very common, notable examples being diamond, silica, and graphite. Polymer materials generally will form crystalline regions, but the lengths of the molecules usually prevents complete crystallization. Weak Van der Waals forces can also play a role in a crystal structure; for example, this type of bonding loosely holds together the hexagonal-patterned sheets in graphite.
Most crystalline materials have a variety of crystallographic defects. The types and structures of these defects can have a profound effect on the properties of the materials, including diffusion deformation.
Gallium, a metal that easily forms large single crystals
A huge monocrystal of potassium dihydrogen phosphate grown from solution by Saint-Gobain for the megajoule laser of CEA.While the term "crystal" has a precise meaning within materials science and solid-state physics, colloquially "crystal" refers to solid objects that exhibit well-defined and often pleasing geometric shapes. In this sense of the word, many types of crystals are found in nature. The shape of these crystals is dependent on the types of molecular bonds between the atoms to determine the structure, as well as on the conditions under which they formed. Snowflakes, diamonds, and common salt are common examples of crystals.
Some crystalline materials may exhibit special electrical properties such as the ferroelectric effect or the piezoelectric effect. Additionally, light passing through a crystal is often bent in different directions, producing an array of colors; crystal optics is the study of these effects. In periodic dielectric structures a range of unique optical properties can be expected as described in photonic crystals.
Crystallography is the scientific study of crystals and crystal formation.
2006-09-06 17:26:10
·
answer #6
·
answered by mysticideas 6
·
1⤊
2⤋