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Solutions of sodium carbonate and silver nitrate react to form solid silver carbonate and a solution of sodium nitrate. A solution containing 8.00 g of sodium carbonate is mixed with one containing 6.75 g of silver nitrate. How many grams of each of the following compounds are present after the reaction is complete?

sodium carbonate

silver nitrate

silver carbonate

sodium nitrate

2006-09-04 07:49:59 · 1 answers · asked by Anonymous in Science & Mathematics Chemistry

1 answers

==Reaction Equation==
1 sodium carbonate+ 2 silver nitrates---> 1 silver carbonate+ 2 sodium nitrates

==Molecular mass==
sodium carbonate = 2*M(Na)+ M(C)+ 3*M(O) = 2*22.99+ 12.01+ 3*16.00 = 105.99 g/mol
silver nitrate = M(Ag)+ M(N)+ 3*M(O) = 107.9+ 14.01+ 3*16.00 =169.91 g/mol
silver carbonate = 2*M(Ag)+ M(C)+ 3*M(O) = 2*107.9+ 12.01+ 3*16.00 = 275.81 g/mol
sodium nitrate = M(Na)+ M(N)+ 3*M(O) = 22.99+ 14.01+ 3*16.00 = 85.00 g/mol

==Before reaction==
Amount in mols of sodium carbonate = 8.00g/(105.99g/mol) = 7.545*10^-2 mol [[01]]

Amount in mols of silver nitrate = 6.75/(169.91) = 3.973*10^-2 mol [[02]]

According to the reaction equation, for every unit of sodium carbonate, we need 2 of silver nitrate. In other words, we need twice as much silver nitrate as sodium carbonate.

However, comparing both [[01]] 7.545*10^-2 and [[02]] 3.973*10^-2, we figure out that we have pretty much about half as much silver nitrate as sodium carbonate. So silver nitrate is said to be the *limiting reactant*.

==Before reaction==
sodium carbonate........... = 7.545*10^-2 mol
silver nitrate..................... = 3.973*10^-2 mol = 2x <--- limiting reactant
silver carbonate............... = 0
sodium nitrate.................. = 0

==Variation due to reaction (according to the stoichiometric coefficients of the reaction equation)==
___ sodium carbonate........... = -x = -1.987*10^-2 mol
___ silver nitrate..................... = -2x = -3.973*10^-2 mol
___ silver carbonate............... = +x = +1.987*10^-2 mol
___ sodium nitrate.................. = +2x = +3.973*10^-2 mol

==After reaction (= before+ variation)==
sodium carbonate............ = 5.559*10^-2 mol----> 5.89 g
silver nitrate...................... = 0
silver carbonate................ = 1.987*10^-2 mol----> 5.48 g
sodium nitrate................... = 3.973*10^-2 mol----> 3.38 g

2006-09-04 08:59:13 · answer #1 · answered by Illusional Self 6 · 1 0

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