Hafnium is a shiny silvery, ductile metal that is corrosion resistant and chemically similar to zirconium. The properties of hafnium are markedly affected by zirconium impurities and these two elements are amongst the most difficult to separate. The only notable difference between them is their density (zirconium is about half as dense as hafnium).
Occurrence
Hafnium is found combined in natural zirconium compounds but it does not exist as a free element in nature. Minerals that contain zirconium, such as alvite [(Hf, Th, Zr)SiO4 H2O], thortveitite and zircon (ZrSiO4), usually contain between 1 and 5% hafnium. Hafnium and zirconium have nearly identical chemistry, which makes the two difficult to separate. About half of all hafnium metal manufactured is produced by a by-product of zirconium refinement. This is done through reducing hafnium(IV) chloride with magnesium or sodium in the Kroll process.
History
Hafnium (Latin Hafnia for "Copenhagen", the home town of Niels Bohr) was discovered by Dirk Coster and Georg von Hevesy in 1923 in Copenhagen, Denmark. Soon after, the new element was predicted to be associated with zirconium by using the Bohr theory and was finally found in zircon through X-ray spectroscope analysis in Norway.
It was separated from zirconium through repeated recrystallization of double ammonium or potassium fluorides by Jantzen and von Hevesey. Metallic hafnium was first prepared by Anton Eduard van Arkel and Jan Hendrik de Boer by passing tetraiodide vapor over a heated tungsten filament.
Hafnium carbide is the most refractory binary compound known and hafnium nitride is the most refractory of all known metal nitrides with a melting point of 3310 °C. This metal is resistant to concentrated alkalis, but halogens react with it to form hafnium tetrahalides. At higher temperatures hafnium reacts with oxygen, nitrogen, carbon, boron, sulfur, and silicon.
The nuclear isomer Hf-178-2m is also a source of energetic gamma rays, and was at one point studied as a possible power source for gamma ray lasers (though this use is now thought to be impossible).
Applications
Hafnium is used to make nuclear control rods, such as those found in nuclear submarines because of its ability to absorb neutrons (its thermal neutron absorption cross section is nearly 600 times that of zirconium), excellent mechanical properties and exceptional corrosion-resistance properties. Other uses:
Used in gas-filled and incandescent lamps,
for scavenging oxygen and nitrogen,
as the electrode in plasma cutting because of its ability to shed electrons into air,
and in iron, titanium, niobium, tantalum, and other metal alloys.
Hafnium dioxide is a candidate for High-K gate insulators in future generations of integrated circuits.
DARPA has been intermittently funding programs to determine the possibility of using a nuclear isomer of hafnium (the above mentioned Hf-178-2m) to construct small, high yield weapons with simple x-ray triggering mechanisms—the hafnium bomb. That work follows over two decades of on-again, off-again enthusiasm for the idea of isomer weapons.
There is considerable scientific opposition to this program, both because the idea may not work and because other countries will use an imagined "isomer weapon gap" to justify nuclear weapons development stockpiling. A related proposal is to use the same isomer to power Unmanned Aerial Vehicles, which could remain airborne for weeks at a time.
Isotopes
All isotopes have 72 protons,
172Hf syn 1.87 years
174Hf 0.162% 2×10^15 years
176Hf 5.206% Hf is stable with 104 neutrons
177Hf 18.606% Hf is stable with 105 neutrons
178Hf 27.297% Hf is stable with 106 neutrons
179Hf 13.629% Hf is stable with 107 neutrons
180Hf 35.1% Hf is stable with 108 neutrons
182Hf syn 9×10^6 years
2006-06-27 07:51:13
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answer #1
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answered by Anonymous
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A brilliant, silvery, metallic element separated from ores of zirconium and used in nuclear reactor control rods, as a getter for oxygen and nitrogen, and in the manufacture of tungsten filaments. Atomic number 72; atomic weight 178.49; melting point 2,220°C; boiling point 5,400°C; specific gravity 13.3; valence 4.
2006-06-27 06:41:34
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answer #2
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answered by tedward the dead turtle 2
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a grey tetravalent metallic element that resembles zirconium chemically and is found in zirconium minerals; used in filaments for its ready emission of electrons
2006-06-27 06:36:06
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answer #3
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answered by Anonymous
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