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When silver ion reacts with iodide ion, silver iodide is formed.

However, silver ion is an oxidising agent, while iodide ion is a reducing agent.

How come this is not a redox reaction?

(If it were a redox, the product would be silver and iodine.)

2007-02-03 07:53:03 · 1 個解答 · 發問者 Anonymous in 科學 化學

1 個解答

Consider the redox reaction between silver ion and iodide ion :
2Ag+(aq) + 2I-(aq) → 2Ag(s) + I2(aq)
Standard e.m.f. of the redox reaction is +0.26 V, and the reaction is feasible.

However, the activation energy of the redox reaction is much higher than that of the precipitation. Therefore, precipitate occurs instead of redox.
Precipitation : Ag+(aq) + Cl-(aq) → AgCl(s)

2007-02-03 08:09:27 · answer #1 · answered by Uncle Michael 7 · 0 0

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