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Increased substituted around a bond leads to increased strain. Take the four substituted butanes listed below, for example. For each compound, sight along the C2-C3 bond and drew Newman projections of the most stable and least stable conformation .Use the in Table 4.1 assign strain energy values to each conformations is most strained?    Which is least strained?   (a)2-Methylbutane              (b)2,2-Dimethylbutane   (c)2,3-Dimethylbutane           (d)2,2,3-Trimethylbutane

2005-10-27 22:09:31 · 2 個解答 · 發問者 Anonymous in 科學 化學

2 個解答

取代基越多,原子團間排斥力造成化學鍵內應力越大。以C2-C3 鍵來看,2,2,3-Trimethylbutane兩個碳上各有兩個及三個甲基,因此化學鍵內應力最大,也就是most strained.
ans.: (d)

2005-10-28 10:34:02 · answer #1 · answered by Anonymous · 0 0

Where is Table 4.1??

2005-10-28 06:27:42 · answer #2 · answered by Frank 7 · 0 0

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